Novel copolymers via nitroxide mediated controlled free radical polymerization of vinyl chloride

被引：31
|
作者：
Wannemacher, T
Braun, D
Pfaendner, R
机构：
[1] Deutsch Kunststoff Inst Darmstadt, D-64289 Darmstadt, Germany
[2] Ciba Spezialitatenchem Lampertheim GmbH, D-68623 Lampertheim, Germany
来源：
MACROMOLECULAR SYMPOSIA | 2003年 / 202卷
关键词：
block copolymers; CFRP; living polymerization; nitroxides; vinyl chloride;
D O I：
10.1002/masy.200351202
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Controlled free radical polymerization (CFRP) of vinyl chloride (VCM) and copolymerization with several comonomers have been studied in aqueous suspension. Therefore di-tert-butyinitroxide and three novel nitroxyl radicals were used as mediating agents. Copolymerization of VCM with styrene, partly combined with acrylonitrile, maleic acid anhydride and maleic acid imide as well as methyl methacrylate, n-butyl methacrylate, butyl acrylate and butadiene have been achieved, demonstrating an efficient route for novel vinyl chloride copolymer architecture.
引用
收藏
页码：11 / 23
页数：13
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