Synthesis and characterization of [Cu(mb2en)2]ClO4 and [Cu(mb2en)(PPh3)2]BPh4:: crystal structure of [Cu(mb2en)2]ClO4

被引：7

作者：

Dehghanpour, Saeed ^{[1
]}

Fotouhi, Lida ^{[1
]}

Amini, Mostafa Mohammadpour ^{[2
]}

Khavasi, Hamid Reza ^{[2
]}

Jahani, Khadijeh ^{[1
]}

Nouroozi, Fatemeh ^{[1
]}

Zamanifar, Elham ^{[1
]}

机构：

[1] Alzahra Univ, Dept Chem, Tehran 1993891176, Iran

[2] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 03期

关键词：

copper(I) complexes; diimine ligand; crystal structure; electrochemistry;

D O I：

10.1080/00958970701360717

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligand, N,N'-bis-(4-methoxy-benzylidene)-ethane-1,2-diamine (mb(2)en), and its corresponding copper(I) complexes, [Cu(mb(2)en)(2)]ClO4 (1), and [Cu(mb(2)en)(PPh3)(2)]BPh4 (2), have been synthesized and characterized by CHN analyses, H-1 and C-13-NMR, IR, and UV-Vis spectroscopies. The crystal and molecular structure of [Cu(mb(2)en)(2)]ClO4 (1), were determined by X-ray crystallography from a single-crystal. The coordination polyhedron about copper(I) is best described as a distorted tetrahedron. Quasi-irreversible redox behavior was observed for 1 and 2 (E-1/2 = 0.55 and 0.95 V, respectively).

引用

页码：455 / 463

页数：9

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