Asymmetric Synthesis of Cyclopropylmethanamines by Rhodium-catalyzed Cyclopropanation of Pinacol Allylboronate with N-Sulfonyl-1,2,3-triazoles

被引：9

作者：

Miura, Tomoya ^{[1
]}

Nakamuro, Takayuki ^{[1
]}

Nikishima, Hiroki ^{[1
]}

Murakami, Masahiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2016年 / 45卷 / 08期

关键词：

Cyclopropylmethanamine; Rhodium catalyst; Triazole; AZAVINYL CARBENES; HETEROCYCLES; TRIAZOLES; BETA; FUNCTIONALIZATION; 1,2,3-TRIAZOLES; REARRANGEMENT; REACTIVITY; ARYLATION; NITROGEN;

D O I：

10.1246/cl.160465

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, the rhodium(II)-catalyzed cyclopropanation reaction of pinacol allylboronate with N-sulfonyl-1,2,3-triazoles is reported. Boryl-substituted cyclopropylmethanamines are produced in a highly diastereo- and enantioselective manner. Various cyclopropylmethanamines containing a quaternary stereocenter are derived from them.

引用

页码：1003 / 1005

页数：3

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