Ring transformations in the reactions of 1,4-dinitropyrazole with N-nucleophiles

被引:18
|
作者
Jedrysiak, Rafal [1 ]
Sawicki, Marcin [1 ]
Wagner, Pawel [1 ]
Suwinski, Jerzy [1 ]
机构
[1] Silesian Tech Univ, Dept Organ Bioorgan Chem & Biotechnol, Gliwice, Poland
关键词
dinitropyrazole; nucleophile; amine; hydrazine; arylnitropyrazole; ring transformation;
D O I
10.3998/ark.5550190.0008.609
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactions of 1,4-dinitropyrazole with primary amines, hydrazines, hydroxylamine and amidines were studied. 1,4-Dinitropyrazole in these reactions served as the synthetic equivalent of nitromalonaldehyde. The reaction of dinitropyrazole with primary arylhydrazines proved to be a convenient approach to the synthesis of 1-aryl-4-nitropyrazoles.
引用
收藏
页码:103 / 111
页数:9
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