Structural and magneto-optical properties of PbO-Bi2O3-B2O3 -Al(PO3)3 glasses

被引：15
|
作者：
An, Hao [1 ]
Qian, Pengyuan [1 ]
Ye, Yumian [1 ]
Wang, Shuangbao [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 2020年 / 538卷
关键词：
Diamagnetic glass; Metaphosphate; Network structure; Verdet constant; Magneto-optical property; FARADAY-ROTATION; BORATE GLASSES; FTIR;
D O I：
10.1016/j.jnoncrysol.2020.120021
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Herein, diamagnetic PbO-Bi2O3-B2O3-Al(PO3)(3) glasses are prepared by melt-casting and the influence of phosphorus tetrahedral on the structure and optical properties of the glass has been systematically investigated. Compared to diamagnetic PbO-Bi2O3-B2O3(PBB) glasses, the original boron chain network has been replaced by the boron-phosphate structure. The metaphosphate forms [PO4] units and expands the glass network, which leads to the decline of density and the increase of refractive index (up to similar to 2.423 @633 nm). The improvement of the magneto-optical properties performs in that the Verdet constant achieves 0.203 min/G cm at 633 nm and higher magneto-optical figure of merit displays a better optical performance than the diamagnetic glass without metaphosphate.
引用
收藏
页数：5
相关论文
共 50 条
  • [1] Effects of gamma irradiation on optical and structural properties of PbO-Bi2O3-B2O3 glasses
    Sharma, Gopi
    Singh, Kulwant
    Manupriya
    Mohan, Shaweta
    Singh, Harvinder
    Bindra, Sukhleen
    [J]. RADIATION PHYSICS AND CHEMISTRY, 2006, 75 (09) : 959 - 966
  • [2] Structure and nonlinear optical properties of PbO-Bi2O3-B2O3 glasses
    Terashima, K
    Shimoto, TH
    Yoko, T
    [J]. PHYSICS AND CHEMISTRY OF GLASSES, 1997, 38 (04): : 211 - 217
  • [3] Optical and electrical properties of SeO2 modified PbO-Bi2O3-B2O3 glasses
    Chen, Qiuling
    Su, Kai
    Zhao, Zhiwei
    Ma, Qiuhua
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2018, 498 : 448 - 454
  • [4] Physical, optical, and ionizing radiation shielding parameters of Al(PO3)3-doped PbO-Bi2O3-B2O3 glass system
    Alothman, Miysoon A.
    Al-Baradi, Ateyyah M.
    Ben Ahmed, Samia
    Kurtulus, Recep
    Olarinoye, I. O.
    Kavas, Taner
    Al-Buriahi, M. S.
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2021, 32 (23) : 27744 - 27761
  • [5] Structural, optical and magnetic properties of Fe3O4 sputtered TeO2-PbO-B2O3 and PbO-Bi2O3-B2O3 glasses for sensing applications
    Chen, Qiuling
    Wang, Hui
    Perero, Sergio
    Wang, Qingwei
    Chen, Qiuping
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2015, 408 : 43 - 50
  • [6] Magneto optical properties of rare earth Tb2O3 doped PbO-Bi2O3-B2O3 glass
    Chen, Qiuling
    Chen, Qiuping
    Wang, Hui
    Wang, Gaimin
    Yin, Shuai
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2017, 470 : 99 - 107
  • [7] VARIATION OF PROPERTIES OF GLASSES ALONG THE 3BI2O3.5B2O3-4PBO.B2O3 AND PBO.2B2O3-2PBO.BI2O3 SECTIONS OF THE PBO-BI2O3-B2O3 TERNARY-SYSTEM
    ZARGAROVA, MI
    SHUSTER, NS
    [J]. INORGANIC MATERIALS, 1985, 21 (02): : 223 - 227
  • [8] PREPARATION AND CHARACTERIZATION OF HIGH-DENSITY PBO-BI2O3-B2O3 GLASSES
    VANKIRK, SE
    MARTIN, SW
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1992, 75 (04) : 1028 - 1031
  • [9] Structure model of glasses for PbO-Bi2O3-B2O3 SYSTEM containing higher B2O3
    Lu, AX
    Huang, JW
    Lu, RW
    [J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 1997, 7 (02) : 141 - 144
  • [10] Dielectric Dispersion in PbO-Bi2O3-B2O3 Glasses Mixed with TiO2
    Rao, P. Venkateswara
    Reddy, M. Srinivasa
    Kumar, V. Ravi
    Gandhi, Y.
    Veeraiah, N.
    [J]. TURKISH JOURNAL OF PHYSICS, 2008, 32 (06): : 341 - 356
12345