Crystal structure of trans-W2(CO)6(PPh2H)2(μ2-PPh2)2

被引：1

作者：

Keiter, RL ^{[1
]}

Martin, JS

Keiter, EA

Rheingold, AL

机构：

[1] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2003年 / 33卷 / 5-6期

关键词：

phosphido-bridged complex; X-ray structure; tungsten carbonyl;

D O I：

10.1023/A:1024254803342

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecular structure of trans-W-2(CO)(6)(PPh2H)(2)(mu(2)-PPh2)(2) was determined by X-ray diffraction analysis. The two tungsten centers, bridged by two diphenylphosphido ligands, are separated by 3.0667(6) Angstrom with W-P-W angles of 77.10(5) and 77.08(5)degrees. Average tungsten-phosphorus bond distances are 2.461(17) and 2.4576(21) Angstrom for bridging and terminal phosphorus groups, respectively, with a range of 0.037 Angstrom for the former and 0.001 Angstrom for the latter. The complex crystallizes in the monoclinic space group P2(1)/c with a = 19.282( 4) Angstrom, b = 12.158( 2) Angstrom, c = 21.294( 9) Angstrom, beta = 92.821( 4)degrees, and Z = 4.

引用

页码：491 / 495

页数：5

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