Thiosemicarbazone-derivatised palladium nanoparticles as efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides with phenylboronic acid

被引：30

作者：

Kovala-Demertzi, Dimitra ^{[1
]}

Kourkoumelis, Nikolaos ^{[2
]}

Derlat, Kinga ^{[1
]}

Michalak, Julita ^{[1
]}

Andreadaki, Fotini J. ^{[3
]}

Kostas, Ioannis D. ^{[3
]}

机构：

[1] Univ Ioannina, Dept Chem, Ioannina 45110, Greece

[2] Univ Ioannina, Dept Phys, Phys Mat Lab, Ioannina 45110, Greece

[3] Natl Hellen Res Fdn, Inst Organ & Pharmaceut Chem, Athens 11635, Greece

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 05期

关键词：

palladium nanoparticles; nanocatalyst; thiosemicarbazone; catalysis; Suzuki-Miyaura cross-coupling;

D O I：

10.1016/j.ica.2007.09.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thiosemicarbazone-derivatised palladium nanoparticles with average crystallite size 16.2 nm have been prepared and characterized by XRD and SEM. The nanoparticles were found to efficiently catalyze the Suzuki-Miyaura cross-coupling of aryl bromides ( from electron-rich to electron poor) with phenylboronic acid even at room temperature, and they can be recovered and reused. (c) 2007 Elsevier B. V. All rights reserved.

引用

页码：1562 / 1565

页数：4

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