Rongalite®-promoted odourless and highly regioselective synthesis of β-hydroxyselenides under solvent-free conditions

被引：7
|
作者：
Lv, Guangshu [1 ]
Li, Ting [1 ]
Hu, Ruijia [1 ]
Chen, Jiuxi [1 ]
Ding, Jinchang [1 ,2 ]
Wu, Huayue [1 ]
机构：
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
[2] Wenzhou Vocat & Tech Coll, Wenzhou 325035, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2010年 / 10期
关键词：
Rongalite (R); beta-hydroxyselenides; grinding; solvent-free conditions; RING-OPENING REACTIONS; DIRECT PERFLUOROALKYLATION; HYDROXY SELENIDES; EPOXIDES; ORGANOSELENIUM; ALKENES; THIOLS; SULFINATODEHALOGENATION; TETRAHYDROFURAN-3-ONES; BENZENESELENOL;
D O I：
10.3184/030823410X12857074253339
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient and facile procedure for the odourless and highly regioselective synthesis of beta-hydroxyselenides by the ring-opening of epoxides with 1,2-diphenyldiselenide in the presence of Rongalite (R) and K2CO3 under solvent-free conditions on grinding has been developed. The important features of this methodology are high yields, reasonably rapid reaction rate, simple workup, high regioselectivity and no requirement for metal catalysts.
引用
收藏
页码：549 / 552
页数：4
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