Rotational transitions in excited vibrational states of D2O

被引：11

作者：

Michael, EA ^{[1
]}

Keoshian, CJ ^{[1
]}

Anderson, SK ^{[1
]}

Saykally, RJ ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2001年 / 208卷 / 02期

基金：

美国国家科学基金会;

关键词：

terahertz; submillimeter; hot D2O spectrum; rotational transitions; excited vibration;

D O I：

10.1006/jmsp.2001.8378

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Rotational transitions of D2O with J < 12 in excited vibrational states (and the ground state) were measured with submegahertz precision in a pulsed discharge supersonic slit expansion of a D2O/NeHe mixture while scanning the range from 1473.69 to 1685.91 GHz using the Berkeley terahertz laser sideband spectrometer. Assignments were made using all available previous IR results, which include the (000), (010), (020), (001), (100), (111), (130), (031), (012), (210), and (121) vibrational states with levels up to 7500 cm(-1). (C) 2001 Academic Press.

引用

页码：219 / 223

页数：5

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