Air-stable, recyclable, and time-efficient diphenylphosphinite cellulose-supported palladium nanoparticles as a catalyst for Suzuki-Miyaura reactions

被引:51
|
作者
Du, Qingwei [1 ]
Li, Yiqun [1 ]
机构
[1] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
diphenylphosphinite cellulose; heterogeneous catalysis; nanopalladium; polymer-supported catalyst; Suzuki-Miyaura reaction; CROSS-COUPLING REACTIONS; IONIC LIQUID IL-OPPH2; ARYL CHLORIDES; HECK REACTION; SONOGASHIRA; LIGAND; BROMIDES; WATER; DEHALOGENATION; COMPLEXES;
D O I
10.3762/bjoc.7.48
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A diphenylphosphinite cellulose palladium complex (Cell-OPPh2-Pd-0) was found to be a highly efficient heterogeneous catalyst for the Suzuki-Miyaura reaction. The products were obtained in good to excellent yield under mild reaction conditions. Moreover, the catalyst could be easily recovered by simple filtration and reused for at least 6 cycles without losing its activity.
引用
收藏
页码:378 / 384
页数:7
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