Synthesis of mesoporous silica single crystal SBA-16 assisted by fluorinated surfactants with short carbon-chains

被引:22
|
作者
Meng, Xiangju [1 ]
Lu, Daling [1 ]
Tatsumi, Takashi [1 ]
机构
[1] Tokyo Inst Technol, Chem Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
基金
日本学术振兴会;
关键词
fluorinated surfactant; single crystal; mesoporous SBA-16; F127;
D O I
10.1016/j.micromeso.2007.05.044
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Single crystals of mesoporous silica SBA-16 in the shape of the rhombododecahedron consisting of twelve flat crystal faces can be obtained by the addition of fluorinated surfactants with short carbon-chains in the presence of nonionic surfactant Pluronic F127. It is proposed that the existence of fluorocarbon parts results in the decrease in the interface surface intension, leading to the formation of single crystals. (C) 2007 Published by Elsevier Inc.
引用
收藏
页码:15 / 23
页数:9
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