Convenient synthesis of [Et4N]2[M2(CO)8(μ-H)2] (M = Mo, W)

被引:1
|
作者
Lin, JT [1 ]
Huang, PH
机构
[1] Acad Sinica, Inst Chem, Taipei, Taiwan
[2] Kang Ning Jr Coll Nursing, Taipei, Taiwan
关键词
D O I
10.1021/om9802562
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
[Et4N](2)[W-2(CO)(8)(mu-H)(2)] and [Et4N](2)[Mo-2(CO)(8)(mu-H)(2)] were synthesized in 47 and 31% yields, respectively, from the reaction of (TMED)M(CO)(4) (M = Mo, W; TMED = N,N,N',N'-tetramethylethylelzediamine) with a stoichiometric quantity of [Et4N][BH4].
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页码:3619 / 3620
页数:2
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