Rongalite-promoted transition metal-free synthesis of S-aryl phosphorothioates

被引：4
|
作者：
Xu, Min-xiao [1 ]
Zhang, Kai-ming [1 ,2 ]
机构：
[1] Jiangsu Police Inst, Nanjing 210031, Peoples R China
[2] Nanjing Inst Technol, Nanjing 211167, Peoples R China
来源：
MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 03期
基金：
中国国家自然科学基金;
关键词：
rongalite; phosphorothioates; arylation; radical process; aryl halides; sulfur; ELEMENTAL SULFUR; PHOSPHORUS; PHOSPHINES; ELECTRON; REAGENT; AMINES;
D O I：
10.1016/j.mencom.2022.05.033
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The improved procedure for the synthesis of S-aryl phosphorothioates from dialkyl phosphites (H-phosphonates), aryl iodides and elemental sulfur deals with the application of rongalite (sodium hydroxy-methanesulfinate) as the radical promoter. The reactions proceeded smoothly to give S-aryl phosphorothioates in good yields.
引用
收藏
页码：390 / 392
页数：3
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