An ambient-temperature aqueous synthesis of zirconium-based metal-organic frameworks

被引：58
|
作者：
Pakamore, Ignas [1 ]
Rousseau, Jolanta [2 ]
Rousseau, Cyril [2 ]
Monflier, Eric [2 ]
Szilagyi, Petra Agota [3 ]
机构：
[1] Univ Greenwich, Dept Pharmaceut Chem & Environm Sci, Medway ME4 4TB, Kent, England
[2] Univ Artois, Univ Lille, CNRS, Cent Lille,ENSCL,UMR 8181,UCCS, F-62300 Lens, France
[3] Queen Mary Univ London, Sch Engn & Mat Sci, Mile End Rd, London E1 4NS, England
来源：
GREEN CHEMISTRY | 2018年 / 20卷 / 23期
基金：
英国工程与自然科学研究理事会;
关键词：
HYBRID POROUS SOLIDS; DRUG-DELIVERY; MODULATED SYNTHESIS; FACILE SYNTHESIS; GAS-STORAGE; UIO-66; DEFECTS; LUMINESCENT; DESIGN;
D O I：
10.1039/c8gc02312c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
For the first time, we have developed an aqueous ambient-temperature synthesis of the zirconium-based metal-organic framework NH2-UiO-66. The optimised synthetic route offers greatly reduced energy input compared with the conventional solvothermal synthetic method and it does not require any organic solvents or vapours. This facile process is easily up-scalable and it yields highly porous nanoparticles. Samples that underwent the reaction in a shorter amount of time displayed point defects of the dangling linker type.
引用
收藏
页码：5292 / 5298
页数：7
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