The oxotungsten(IV) complex [WOCl(Ph2PCH2CH2PPh2)2]PF6.CHCl3

被引：0

作者：

Llusar, R

Mata, J

Peris, E

Köckerling, M

机构：

[1] Univ Jaume 1, Dept Expt Sci, Castellon de La Plana 12080, Spain

[2] Univ Jaume 1, Dept Inorgan & Organ Chem, Castellon de La Plana 12080, Spain

[3] Univ Duisburg Gesamthsch, Inst Synth Chem, D-47057 Duisburg, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198015856

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystals of the title compound, chlorobis[ethylene-bis(diphenylphosphine-P)]oxotungsten(IV) hexafluorophosphate trichloromethane solvate, [WOCl(C26H24P2)(2)]PF6.CHCl3, contain mononuclear tungsten complex molecules. The W atoms are octahedrally coordinated by two bidentate phosphine ligands and one Cl atom which is located trans to an O atom. The W-O distance is 1.851(3) Angstrom and the mean O-W-P angle is 94 (5)degrees. In contrast to the reported structure for an analogous cationic tungsten complex, the Cl- and O-atom positions do not show disorder.

引用

页码：506 / 508

页数：3

共 50 条

[1] Oxotungsten(IV) complex [WOCl(Ph2PCH2CH2PPh2)2]PF6·CHC l3
Llusar, R.
Mata, J.
Peris, E.
Kockerling, M.
[J]. Acta Crystallographica, Section C: Crystal Structure Communications, 1999, 55 (pt 4): : 506 - 508
[2] REDETERMINATION OF STRUCTURE OF [IRO2(PH2PCH2CH2PPH2)2][PF6]
NOLTE, MJ
SINGLETON, E
LAING, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (22) : 6396 - 6400
[3] NICKEL NITROSYL COMPLEXES WITH DIPHOSPHINES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(PH2PCH2CH2PPH2)(ON)NI(MU-PH2PCH2CH2PPH2)NI(NO)(PH2PCH2CH2PPH2)][BF4]2
DEL ZOTTO, A
MEZZETTI, A
NOVELLI, V
RIGO, P
LANFRANCHI, M
TIRIPICCHIO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03): : 1035 - 1042
[4] GENERATION AND INTERCONVERSIONS OF THE DI-NUCLEAR AND TRI-NUCLEAR PLATINUM COMPLEXES [PT2H2(PH2PCH2CH2PPH2)2], [PT2H3(PH2PCH2CH2PPH2)2]+, AND [PT3H3(PH2PCH2CH2PPH2)3]+ - CRYSTAL AND MOLECULAR-STRUCTURE OF [PT3H3(PH2PCH2CH2PPH2)3]+[BET4]-
CARMICHAEL, D
HITCHCOCK, PB
NIXON, JF
PIDCOCK, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (23) : 1554 - 1556
[5] STRUCTURAL CHARACTERIZATION OF 2 OXOTUNGSTEN(IV) COMPLEXES, [WOCL(ME2PCH2CH2PME2)2]CLO4 AND [WOCL(ME2PCH2P(S)ME2)2]PF6
COTTON, FA
LLUSAR, R
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 : 952 - 955
[6] CHARACTERIZATION OF REPORTED [MN(CO)(PH2PCH2CH2PPH2)2] (RED ISOMER) AS ACYLMANGANESE COMPLEX[MN(CO)(COC6H4PHPCH2CH2PPH2)(PH2PCH2CH2PPH2)]BY X-RAY-DIFFRACTION
LAING, M
TREICHEL, PM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (18) : 746 - 746
[7] SPECTROSCOPIC ASSIGNMENTS OF THE EXCITED-STATES OF TRANS-(N2)2W(PH2PCH2CH2PPH2)2 MO(PH2PCH2CH2PPH2)2
BRUMMER, JG
CROSBY, GA
[J]. INORGANIC CHEMISTRY, 1985, 24 (04) : 552 - 558
[8] REGIOSELECTIVITY OF HYDRIDE ADDITION TO [(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)CO]PF6 AND REARRANGEMENT OF "(ETA-5-C5H5)FE(PH2PCH2CH2PPH2)(CO)H TO (ETA-4-C5H6)FE(PH2PCH2CH2PPH2)CO
DAVIES, SG
HIBBERD, J
SIMPSON, SJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 246 (01) : C16 - C18
[9] CYCLIZATION OF UNSATURATED ALDEHYDES CATALYZED BY (PPH3)2CO(PH2PCH2CH2PPH2)
VINOGRADOV, MG
TUZIKOV, AB
NIKISHIN, GI
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (11): : 2353 - 2356
[10] REACTIONS OF 1-ALKYNES WITH TRANS-[RECL(N2)(PH2PCH2CH2PPH2)2] - PREPARATION OF THE VINYLIDENE COMPOUNDS TRANS-[RECL(=C=CH-ALKYL)(PH2PCH2CH2PPH2)2], TRANS-[RECL(=C=CH-ARYL)(PH2PCH2CH2PPH2)2] AND X-RAY STRUCTURE OF TRANS-[RECL(=C=CHPH)-(PH2PCH2CH2PPH2)2]
POMBEIRO, AJL
ALMEIDA, SSPR
SILVA, MFCG
JEFFREY, JC
RICHARDS, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (12): : 2381 - 2387

← 1 2 3 4 5 →