Aspects of electron transfer processes in vanadium redox-flow batteries

被引：44
|
作者：
Roznyatovskaya, Nataliya [1 ,2 ]
Noack, Jens [1 ,2 ]
Pinkwart, Karsten [1 ,2 ]
Tuebke, Jens [1 ,2 ]
机构：
[1] Fraunhofer Inst Chem Technol Appl Electrochem, Joseph Von Fraunhofer Str 7, D-76327 Pfinztal, Germany
[2] UNSW, German Australian Alliance Electrochem Technol St, Unsw Sydney, NSW 2052, Australia
来源：
CURRENT OPINION IN ELECTROCHEMISTRY | 2020年 / 19卷
关键词：
Vanadium redox-flow battery; Vanadium electrode reactions; Kinetics; TRANSFER KINETICS; GLASSY-CARBON; ELECTROCHEMICAL TREATMENT; OXIDATION REACTION; FELT ELECTRODES; MECHANISM; PERFORMANCE; REDUCTION; GRAPHITE; CELL;
D O I：
10.1016/j.coelec.2019.10.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electrochemical processes in vanadium redox-flow batteries (VRFBs) include conversions of vanadium species in acidic electrolytes with total vanadium concentrations over molar range. The majority of currently available data on electrode kinetics of vanadium reactions, and on the role of electrode surface chemistry are obtained for diluted electrolyte solutions and are very controversial. In this minireview, we consider the interpretations of electrochemical kinetic data for vanadium electrode reactions and mechanistic concepts, which have been reported in the literature. Thereby, the gap between electrochemical kinetics in "diluted" and "concentrated" solutions is in the focus of the review.
引用
收藏
页码：42 / 48
页数：7
相关论文
共 50 条
  • [1] Redox-targeted catalysis for vanadium redox-flow batteries
    Zhang, Feifei
    Huang, Songpeng
    Wang, Xun
    Jia, Chuankun
    Du, Yonghua
    Wang, Qing
    [J]. NANO ENERGY, 2018, 52 : 292 - 299
  • [2] Preparation of Electrolyte for Vanadium Redox-Flow Batteries Based on Vanadium Pentoxide
    Martin, Jan
    Schafner, Katharina
    Turek, Thomas
    [J]. ENERGY TECHNOLOGY, 2020, 8 (09)
  • [3] Low-Cost Membranes for Vanadium Redox-Flow Batteries
    Dueerkop, Dennis
    Widdecke, Hartmut
    Kunz, Ulrich
    Schilde, Carsten
    Schmiemann, Achim
    [J]. CHEMIE INGENIEUR TECHNIK, 2021, 93 (09) : 1445 - 1450
  • [4] Vanadium Electrolyte for All-Vanadium Redox-Flow Batteries: The Effect of the Counter Ion
    Roznyatovskaya, Nataliya
    Noack, Jens
    Mild, Heiko
    Fuehl, Matthias
    Fischer, Peter
    Pinkwart, Karsten
    Tuebke, Jens
    Skyllas-Kazacos, Maria
    [J]. BATTERIES-BASEL, 2019, 5 (01):
  • [5] The influence of electrochemical treatment on electrode reactions for vanadium redox-flow batteries
    Jens Noack
    Nataliya Roznyatovskaya
    Jessica Kunzendorf
    Maria SkyllasKazacos
    Chris Menictas
    Jens Tbke
    [J]. Journal of Energy Chemistry, 2018, 27 (05) : 1341 - 1352
  • [6] Tuning the Perfluorosulfonic Acid Membrane Morphology for Vanadium Redox-Flow Batteries
    Vijayakumar, M.
    Luo, Qingtao
    Lloyd, Ralph
    Nie, Zimin
    Wei, Xiaoliang
    Li, Bin
    Sprenkle, Vincent
    Londono, J-David
    Unlu, Murat
    Wang, Wei
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (50) : 34327 - 34334
  • [7] The influence of electrochemical treatment on electrode reactions for vanadium redox-flow batteries
    Jens Noack
    Nataliya Roznyatovskaya
    Jessica Kunzendorf
    Maria Skyllas-Kazacos
    Chris Menictas
    Jens Tübke
    [J]. Journal of Energy Chemistry, 2018, (05) : 1341 - 1352
  • [8] Sustainability of vanadium redox-flow batteries: Benchmarking electrolyte synthesis procedures
    Dassisti, M.
    Cozzolino, G.
    Chimienti, M.
    Rizzuti, A.
    Mastrorilli, P.
    L'Abbate, P.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (37) : 16477 - 16488
  • [9] The influence of electrochemical treatment on electrode reactions for vanadium redox-flow batteries
    Noack, Jens
    Roznyatovskaya, Nataliya
    Kunzendorf, Jessica
    Skyllas-Kazacos, Maria
    Menictas, Chris
    Tuebke, Jens
    [J]. JOURNAL OF ENERGY CHEMISTRY, 2018, 27 (05) : 1341 - 1352
  • [10] The Chemistry of Redox-Flow Batteries
    Noack, Jens
    Roznyatovskaya, Nataliya
    Herr, Tatjana
    Fischer, Peter
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (34) : 9775 - 9808
12345