A facile approach to new vinylogous tetrathiafulvalene (TTF) derivatives: 2,3-bis(1,3-dithiole-2-ylidene)succinonitriles

被引:5
|
作者
Jia, CY
Liu, SX
Neels, A
Stoeckli-Evans, H
Decurtins, S
机构
[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland
[2] Univ Neuchatel, Inst Chim, CH-2007 Neuchatel, Switzerland
来源
SYNTHESIS-STUTTGART | 2005年 / 13期
关键词
cycloadditions; substituent effects; sulfur; synthesis; vinylogous tetrathiafulvalene;
D O I
10.1055/s-2005-869997
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new approach to vinylogous TTF derivatives 5 via an alkyne-coupling reaction is reported. Their fundamental redox behavior has been studied. A proposed reaction mechanism, which accounts for the formation of compounds 5 is discussed.
引用
收藏
页码:2157 / 2160
页数:4
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