Influence of Alteration Solutions on the Chemical Durability of the Zerodur® Glass-Ceramic: Structural Investigation

被引:6
|
作者
Doret, Alexandre [1 ,2 ]
Pellerin, Nadia [1 ]
Allix, Mathieu [1 ]
Pellerin, Stephane [2 ]
Lena, Vincent [3 ]
Perrigaud, Katy [4 ]
Massiot, Dominique [1 ,5 ]
机构
[1] Univ Orleans, CNRS, CEMHTI UPR3079, F-45071 Orleans, France
[2] Univ Orleans CNRS, GREMI, UMR 7344, F-18028 Bourges, France
[3] SAFRAN Sagem, Etab Montlucon, F-03106 Montlucon, France
[4] Ecole Mines Nantes, SUBATECH, UMR CNRS IN2P3 6457, F-44307 Nantes, France
[5] CNRS, Inst Chim, F-75794 Paris, France
关键词
LAYERED SODIUM DISILICATE; ALUMINOSILICATE GLASSES; HYDRATION PROCESS; NMR; STATE; SPECTROSCOPY; SILICA; SURFACE; WATER; MECHANISMS;
D O I
10.1111/ijac.12270
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The Zerodur((R)) glass-ceramic chemical durability has been studied by leaching. The nuclear magnetic resonance spectroscopy analysis has allowed highlighting the network changes. A macroscopic evaluation of the surface alteration has been performed by contact angle measurements, this analysis being sensible to the roughness and the hydrophilic character. In basic solutions, depolymerization phenomena concern all former cations, as result of hydrolysis phenomena. A preferential attack of the interface matrix-nanocrystals, implicating phosphorus involves some nanocrystals removing. The Zerodur((R)) glass-ceramic keeps an excellent chemical durability during exposition to acidic aqueous solutions. But in basic medium, the biphasic nature involves a strong alteration.
引用
收藏
页码:811 / 822
页数:12
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