Diels-Alder reactivity of 4-aryl-1-phthalimido-2-siloxy-1,3-butadienes

被引：6
|
作者：
Caballero, E
Alonso, D
Peláez, R
Alvarez, N
Puebla, P
Sanz, F
Medarde, M
Tomé, F
机构：
[1] Univ Salamanca, Fac Farm, Lab Quim Organ & Farmaceut, E-37007 Salamanca, Spain
[2] Serv Difracc Rayos X, Salamanca, Spain
来源：
TETRAHEDRON | 2005年 / 61卷 / 28期
关键词：
aminosiloxybutadienes; synthesis; Diels-Alder;
D O I：
10.1016/j.tet.2005.04.076
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of (1Z,3E) and (1E,3E) 4-aryl-1-phthalimido-2-trialkylsiloxy-1,3-butadienes with maleimides and quinones has been studied. The observed exo-stereospecifity can be attributed to the simultaneous presence of the phthalimido and aryl groups, which produce strong hindrance during the endo approach. (c) 2005 Elsevier Ltd. All rights reserved.
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收藏
页码：6871 / 6878
页数：8
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