Principles of Ethanol Organosolv Lignin Precipitation: Process Simulation and Energy Demand

被引:19
|
作者
Weinwurm, Felix [1 ]
Drljo, Adela [1 ]
Silva, Tania L. S. [2 ]
Friedl, Anton [1 ]
机构
[1] Vienna Univ Technol, Inst Chem Engn, Getreidemarkt 9-166-2, A-1060 Vienna, Austria
[2] Univ Minho, Dept Biol Engn, P-4719 Braga, Portugal
关键词
D O I
10.3303/CET1439098
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study focuses on ways to precipitate lignin, and how the choice of pr-econcentration technique affects an ethanol organosolv (EOS) processes' energy and chemicals demand. Experiments were performed in order to precipitate lignin from an EOS treatment liquor by a) direct precipitation with sulphuric acid, b) vacuum-assisted evaporation and acid precipitation, and c) concentration by nanofiltration and acid precipitation. Utilizing the process simulation tool ASPEN Plus (R), supported by experimental data, energy and chemical demand were calculated. It was shown that chemicals demand decreased significantly by preconcentration and that the energy demand for the nanofiltration case was considerably lower than in the evaporation case.
引用
收藏
页码:583 / +
页数:2
相关论文
共 50 条
  • [1] Advanced process for precipitation of lignin from ethanol organosolv spent liquors
    Schulze, Peter
    Seidel-Morgenstern, Andreas
    Lorenz, Heike
    Leschinsky, Moritz
    Unkelbach, Gerd
    [J]. BIORESOURCE TECHNOLOGY, 2016, 199 : 128 - 134
  • [2] Lignin precipitation on the pulp fibers in the ethanol-based organosolv pulping
    Xu, Yongjian
    Li, Kecheng
    Zhang, Meiyun
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 301 (1-3) : 255 - 263
  • [3] Effects of process severity on the chemical structure of Miscanthus ethanol organosolv lignin
    El Hage, Roland
    Brosse, Nicolas
    Sannigrahi, Poulomi
    Ragauskas, Arthur
    [J]. POLYMER DEGRADATION AND STABILITY, 2010, 95 (06) : 997 - 1003
  • [4] Catalytic hydrogenolysis of ethanol organosolv lignin
    Nagy, Mate
    David, Kasi
    Britovsek, George J. P.
    Ragauskas, Arthur J.
    [J]. HOLZFORSCHUNG, 2009, 63 (05) : 513 - 520
  • [5] Effects of Ethanol Concentration on Organosolv Lignin Precipitation and Aggregation from Miscanthus x giganteus
    Hamzah, Muhammad Hazwan
    Bowra, Steve
    Cox, Philip
    [J]. PROCESSES, 2020, 8 (07)
  • [6] Characterization of Miscanthus giganteus Lignin Isolated by Ethanol Organosolv Process under Reflux Condition
    Bauer, Stefan
    Sorek, Hagit
    Mitchell, Valerie D.
    Ibanez, Ana B.
    Wemmer, David E.
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (33) : 8203 - 8212
  • [7] Removal of residual lignin of ethanol-based organosolv pulp by an alkali extraction process
    Zhang, Meiyun
    Xu, Yongjian
    Li, Kecheng
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 106 (01) : 630 - 636
  • [8] Characterization of milled wood lignin and ethanol organosolv lignin from miscanthus
    El Hage, Roland
    Brosse, Nicolas
    Chrusciel, Laurent
    Sanchez, Christian
    Sannigrahi, Poulomi
    Ragauskas, Arthur
    [J]. POLYMER DEGRADATION AND STABILITY, 2009, 94 (10) : 1632 - 1638
  • [9] Structural Characterization of Switchgrass Lignin after Ethanol Organosolv Pretreatment
    Hu, Gang
    Cateto, Carolina
    Pu, Yunqiao
    Samuel, Reichel
    Ragauskas, Arthur J.
    [J]. ENERGY & FUELS, 2012, 26 (01) : 740 - 745
  • [10] Insights of Ethanol Organosolv Pretreatment on Lignin Properties of Broussonetia papyrifera
    Yao, Lan
    Chen, Congxin
    Yoo, Chang Geun
    Meng, Xianzhi
    Li, Mi
    Pu, Yunqiao
    Ragauskas, Arthur J.
    Dong, Chengyu
    Yang, Haitao
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (11): : 14767 - 14773