Charge-compensated carbarhodaboranes.: Synthesis and molecular structures of 3-L-3,3-(I)2-4-SMe2-3,1,2-closo-RhC2B9H10, L = CO or PPh3

被引：10

作者：

Boyd, ASF ^{[1
]}

Rosair, GM ^{[1
]}

Tiarks, FBH ^{[1
]}

Weller, AS ^{[1
]}

Zahn, SK ^{[1
]}

Welch, AJ ^{[1
]}

机构：

[1] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

POLYHEDRON | 1998年 / 17卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

carbaborane; rhodium; synthesis; structure;

D O I：

10.1016/S0277-5387(98)00011-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 3,3-(CO)(2)-4-SMe2-3,1,2-closo-RhC2B9H10 with iodine results in the formation of 3-(CO)-3,3-(I)(2)-4-SMe2-3,1,2-closo-RhC2B9H10, 1. Reaction between 1 and PPh3 results in substitution of the carbonyl group to afford 3-PPh3-3,3-(I)(2)-4-SMe2-3, 1, 2-closo-RhC2B9H10, 2. Both new compounds have been fully characterised by multinuclear NMR spectroscopy and also by a single crystal X-ray diffraction studies. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2627 / 2632

页数：6

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