Synthesis of bis(2-pyridylthio)methyl zinc hydride and catalytic hydrosilylation and hydroboration of CO2

被引：13
|
作者：
Shlian, Daniel G. [1 ]
Amemiya, Erika [1 ]
Parkin, Gerard [1 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 26期
关键词：
CARBON-DIOXIDE; REACTIVITY; COORDINATION; REDUCTION; COMPLEXES; BOND; CARBOXYLATE; GENERATION; INSERTION; COMPOUND;
D O I：
10.1039/d1cc06963b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of bis(2-pyridylthio)methane with Me2Zn and Zn[N(SiMe3)(2)](2) afford [Bptm]ZnMe and [Bptm]ZnN(SiMe3)(2), thereby providing access to a variety of other [Bptm]ZnX derivatives, including the zinc hydride complex [Bptm]ZnH, which serves as a catalyst for the reduction of CO2 and other carbonyl compounds via hydrosilylation and hydroboration.
引用
收藏
页码：4188 / 4191
页数：4
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