Synthesis, structure and characterization of Schiff base metal complexes and their electrochemical properties of thionyl chloride reduction

被引：5

作者：

Che Tu-Lin ^{[1
]}

Gao Quan-Chang ^{[1
]}

Zhao Jian-She ^{[1
]}

Zhang Gai ^{[1
]}

机构：

[1] NW Univ Xian, Minist Educ, Dept Chem, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Shaanxi, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2008年 / 26卷 / 06期

关键词：

transition metal complex of Schiff base; lithium-thionyl chloride battery; catalyst;

D O I：

10.1002/cjoc.200890191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A symmetric tetradentate Schiff base ligand bis(3-methoxysalicylidene)-o-phenylenediamine (H2L) was prepared. A series of transition metal complexes with this Schiff base ligand have been synthesized and structurally characterized by IR and elemental analysis. The catalysis for reduction of thionyl chloride was studied by means of constant resistance discharge. The result shows that [Mn(III)LCl(H2O)]CH3OH and [Co(II)HLCl(H2O)] have a good catalytic activity for the reduction of thionyl chloride, which improves the cell voltage, the rate of discharge, and the lifetime of Li/SOCl2 batteries.

引用

页码：1079 / 1084

页数：6

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