Raman study of aluminum chloride dimethylsulfone solutions

被引：45

作者：

Legrand, L ^{[1
]}

Tranchant, A ^{[1
]}

Messina, R ^{[1
]}

Romain, F ^{[1
]}

Lautie, A ^{[1
]}

机构：

[1] LAB SPECTROCHIM INFRA ROUGE & RAMAN,CNRS,UPR 2631,F-94320 THIAIS,FRANCE

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 05期

关键词：

D O I：

10.1021/ic941455q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Raman spectra of AlCl3-LiCl-dimethylsulfone mixtures with different molar compositions have been recorded as a solid (300 K) and as a melt (400 K). In any case, only AlCl4- ion lines at 120, 179, and 347 cm(-1) were observed; we were unable to detect any other chloroaluminate species. Furthermore, some bands assigned to the Al[(CH3)(2)SO2](3+)(3) octahedral coordination compound are evidence for a high AlCl3 content.

引用

页码：1310 / 1312

页数：3

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