Towards the sustainable production of pyridines via thermo-catalytic conversion of glycerol with ammonia over zeolite catalysts

In this study, renewable pyridines could be directly produced from glycerol and ammonia via a thermocatalytic conversion process with zeolites. The major factors, including catalyst, temperature, weight hourly space velocity (WHSV) of glycerol to catalyst, and the molar ratio of ammonia to glycerol, which may affect the pyridine production, were investigated systematically. The optimal conditions for producing pyridines from glycerol were achieved with HZSM-5 (Si/Al = 25) at 550 degrees C with a WHSV of glycerol to catalyst of 1 h(-1) and an ammonia to glycerol molar ratio of 12 : 1. The carbon yield of pyridines was up to 35.6%. The addition of water to the feed decreased the pyridine yield, because water competed with glycerol on the acid sites of the catalyst and therefore impacted the acidity of the catalyst. After five reaction/regeneration cycles, a slight deactivation of the catalyst was observed. The catalysts were investigated by N-2 adsorption/desorption, XRD, XRF and NH3-TPD and the results indicated that the deactivation could be due to the structure changes and the acid site loss of the catalyst. The reaction pathway from glycerol to pyridines was studied and the main pathway should be that glycerol was initially dehydrated to form acrolein and some by-products such as acetaldehyde, acetol, acetone, etc., and then acrolein, a mixture of acrolein and acetaldehyde, or other by-products reacted with ammonia to form imines and finally pyridines.