Synthesis and Catalytic Properties of Ordered Mesoporous Phenol-Formaldehyde Resins as Solid Acid Catalysts

被引：0

作者：

Mou Li ^{[1
]}

Qu Xue-Jian ^{[2
]}

Wang Chun-Yan ^{[3
]}

机构：

[1] Changchun Univ, Sch Biosci & Technol, Changchun 130023, Peoples R China

[2] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China

[3] Jilin Univ, Sch Publ Hlth, Changchun 130012, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2010年 / 31卷 / 08期

关键词：

Solid acid catalyst; Ordered mesopores; Phenol-formaldehyde resins; Esterification; Acylation; CARBON FRAMEWORKS; HETEROPOLY ACIDS; POLYMERS; ROUTE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel ordered mesoporous solid acid catalyst (FDU-16-SO(3)H) was prepared by sulfonation of mesoporous polymers( FDU-16). The sample was carefully investigated by XRD, N(2) adsorption, TEM and IR. Characterization results suggested that the mesostructure of the sample was retained during the sulfonation. Catalytic esterification and acylation over FDU-16-SO(3)H show high catalytic activities, which is attributed the strong acidity, mesoporous structure and hydrophobic framework. Excellent catalytic properties ensure such mesoporous solid acid great potential application in industry.

引用

页码：1643 / 1646

页数：4

共 18 条

[1] Environmentally friendly catalytic methods
Clark, JH
Macquarrie, DJ
[J]. CHEMICAL SOCIETY REVIEWS, 1996, 25 (05) : 303 - &
[2] INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS
CORMA, A
[J]. CHEMICAL REVIEWS, 1995, 95 (03) : 559 - 614
[3] From microporous to mesoporous molecular sieve materials and their use in catalysis
Corma, A
[J]. CHEMICAL REVIEWS, 1997, 97 (06) : 2373 - 2419
[4] Influence of the alkyl chain length of HSO3-R-MCM-41 on the esterification of glycerol with fatty acids
Díaz, I
Mohino, F
Blasco, T
Sastre, E
Pérez-Pariente, J
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 80 (1-3) : 33 - 42
[5] SOLID CATALYST TREATED WITH ANION .2. REACTIONS OF BUTANE AND ISOBUTANE CATALYZED BY ZIRCONIUM-OXIDE TREATED WITH SULFATE ION - SOLID SUPERACID CATALYST
HINO, M
KOBAYASHI, S
ARATA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (21) : 6439 - 6441
[6] Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions
Kozhevnikov, IV
[J]. CHEMICAL REVIEWS, 1998, 98 (01) : 171 - 198
[7] HETEROPOLY ACIDS AND RELATED-COMPOUNDS AS CATALYSTS FOR FINE CHEMICAL SYNTHESIS
KOZHEVNIKOV, IV
[J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1995, 37 (02): : 311 - 352
[8] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM
KRESGE, CT
LEONOWICZ, ME
ROTH, WJ
VARTULI, JC
BECK, JS
[J]. NATURE, 1992, 359 (6397) : 710 - 712
[9] Transesterification of triacetin with methanol on Nafion® acid resins
Lopez, Dora E.
Goodwin, James G., Jr.
Bruce, David A.
[J]. JOURNAL OF CATALYSIS, 2007, 245 (02) : 381 - 391
[10] Advances in the synthesis and catalytic applications of organosulfonic-functionalized mesostructured materials
Melero, Juan A.
van Grieken, Rafael
Morales, Gabriel
[J]. CHEMICAL REVIEWS, 2006, 106 (09) : 3790 - 3812

← 1 2 →