Synthetic routes to 11-oxygenated 14α,17α-ethanoestradiols

被引：0
|
作者：
Bull, JR [1 ]
de Koning, PD
机构：
[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa
[2] ChiroTech Technol Ltd, Cambridge CB4 0WE, England
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 2001卷 / 06期
关键词：
steroids; estradiol analogues; hormones; epoxidations; hydroborations;
D O I：
10.1002/1099-0690(200103)2001:6<1189::AID-EJOC1189>3.0.CO;2-H
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Methods are described for the selective transformation of Delta (9(11)) derivatives of 14 alpha ,17 alpha -ethanoestradiol into their 11-oxygenated analogues by epoxidation-rearrangement or hydroboration-oxidation reaction sequences.
引用
收藏
页码：1189 / 1193
页数：5
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