Asymmetric synthesis of cyclopropanes from lithiated aryloxiranes and α,β-unsaturated Fischer carbene complexes

被引：31
|
作者：
Capriati, V
Florio, S
Luisi, R
Perna, FM
Barluenga, J
机构：
[1] Univ Bari, Dipartimento Farmaco Chim, I-70126 Bari, Italy
[2] Univ Oviedo, CSIC, Inst Univ Quim Organometal Enrique Moles, E-33006 Oviedo, Spain
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 15期
关键词：
D O I：
10.1021/jo050443r
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A diastereo- and enantiospecific formation of tetrasubstituted cyclopropane carbene complexes and cyclopropanecarboxylates from lithiated aryloxiranes and alpha,beta-unsaturated Fischer carbene complexes is described.
引用
收藏
页码：5852 / 5858
页数：7
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