Synthesis, crystal structures and luminescence properties of two novel 3D heterometallic coordination polymers

被引:13
|
作者
Zhang, Wan-zhong [1 ,2 ]
Lv, Tian-yi [1 ]
Wei, De-zhou [2 ]
Xu, Rui [1 ]
Xiong, Gang [1 ]
Wang, Yu-qi [1 ]
Gao, En-jun [1 ]
Sun, Ya-guang [1 ]
机构
[1] Shenyang Univ Chem Technol, Lab Coordinat Chem, Shenyang 110142, Peoples R China
[2] Northeastern Univ, Sch Resource & Civil Engn, Shenyang 110004, Peoples R China
关键词
Heterometallic; Coordination polymers; Crystal structure; Luminescence; PYRIDINE-2,4,6-TRICARBOXYLIC ACID; METAL; COMPLEXES; MOLECULES; CLUSTERS; ION;
D O I
10.1016/j.inoche.2011.04.032
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two heterometallic coordination polymers, {KBa(ptc)(H2O)(2)}(n)(1) and {KCaEr(ptc)(2)(H2O)}(n)(2) (H(3)ptc= pyridine-2,4,6-tricarboxylic acid) have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR and single crystal X-ray diffraction. 1 and 2 exhibit two novel three-dimensional (3D) frameworks, and the luminescence properties of 1,2 were investigated. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1245 / 1249
页数:5
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