A Gd-based borate-carbonate framework exhibiting a large magnetocaloric effect at a low magnetic field

被引：6
|
作者：
Liu, Bo-Liang [1 ,2 ]
Xu, Qiao-Fei [1 ,2 ]
Long, La-Sheng [1 ,2 ]
Zheng, Lan-Sun [1 ,2 ]
机构：
[1] Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[2] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
来源：
DALTON TRANSACTIONS | 2021年 / 50卷 / 37期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; THERMAL-CONDUCTIVITY; DEMAGNETIZATION; CAGE;
D O I：
10.1039/d1dt02624k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3D borate-carbonate framework, GdB(OH)(4)CO3 (1), was synthesized. Magnetic study reveals that its MCE is up to 33.5 J kg(-1) K-1 at 2 K and 2 T, due to the introduction of a long magnetic exchange path of Gd-O-B-O-Gd leading to 1 exhibiting weak magnetic interaction.
引用
收藏
页码：12831 / 12834
页数：4
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