Copper-Catalyzed Methylthiolation of Aryl Iodides and Bromides with Dimethyl Disulfide in Water

被引：6
|
作者：
Wang, Ying-yu [1 ]
Wu, Xiang-mei [1 ]
Yang, Ming-hua [1 ]
机构：
[1] Lishui Univ, Dept Chem, Lishui 323000, Zhejiang, Peoples R China
来源：
SYNLETT | 2020年 / 31卷 / 12期
基金：
中国国家自然科学基金;
关键词：
methylthiolation; aryl halides; dimethyl disulfide; aryl methyl sulfides; copper catalysis; CROSS-COUPLING REACTIONS; C-S ACTIVATION; METHYL SULFIDES; CARBON-SULFUR; IMIDAZOLE INHIBITORS; PROBING SUBSTITUENTS; ARYLBORONIC ACIDS; CYTOKINE RELEASE; IPSO-BORYLATION; NICKEL-CATALYST;
D O I：
10.1055/s-0040-1707131
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient route to aryl methyl sulfides through the copper-catalyzed coupling reaction of aryl iodides or bromides with dimethyl disulfide in water is described. Electron-donating and electron-withdrawing functional groups in the substrates were tolerated, and the corresponding products were obtained in moderate to good yields.
引用
收藏
页码：1226 / 1230
页数：5
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