Fokker-Planck equations for stochastic diffusion associated with Markovian electrochemical noise

被引:5
|
作者
Grafov, B. M. [1 ]
机构
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119071, Russia
关键词
electrochemical noise; stochastic diffusion; electrochemical noise diagnosis; IRREVERSIBLE-PROCESSES; RECIPROCAL RELATIONS;
D O I
10.1134/S1023193515030064
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The theoretical analysis of quadratic correlations of equilibrium electrical fluctuations in the Markovian electrochemical ac circuit is accomplished. The modified Fokker-Plank equation which allows one to follow the time evolution of 2nd-order correlators of electrochemical stochastic diffusion associated with the Markovian electrochemical ac circuit (Eq. (7)) is obtained. Due to interdisciplinary significance of the random process theory, the resulting Fokker-Planck equation is also of certain interest for the general theory of stochastic phenomena occurring near the equilibrium state. The derived modified Fokker-Planck equation can be used in the electrochemical noise diagnosis as the Markovian standard of electrochemical stochastic diffusion.
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页码:278 / 280
页数:3
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