Exploration of the mechanism of enhanced CMAS corrosion resistance at 1500?C for multicomponent (Er0.25Tm0.25Yb0.25Lu0.25)2Si2O7 disilicate

被引:27
|
作者
Sun, Luchao [1 ]
Ren, Xiaomin [1 ,2 ]
Luo, Yixiu [1 ]
Lv, Xirui [1 ,2 ]
Wang, Jiemin [1 ]
Oh, Yoonsuk [3 ]
Wang, Jingyang [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
[2] Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
[3] Korea Inst Ceram Engn & Technol, Icheon 17303, South Korea
基金
中国国家自然科学基金;
关键词
Environmental barrier coating; Rare-earth disilicate; Multicomponent design; CMAS corrosion; ENVIRONMENTAL BARRIER COATINGS; SILICATE; GLASS; DEGRADATION; CERAMICS; TEMPERATURE; PROGRESS; ATTACK; RE;
D O I
10.1016/j.corsci.2022.110343
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
(Er0.25Tm0.25Yb0.25Lu0.25)(2)Si2O7 with excellent CMAS corrosion resistance has been designed for the application of environmental barrier coating. The mechanisms governing the enhancement was disclosed through experi-mental investigations of the bulk sample corroded by highly corrosive CMAS melts at 1500 ? for 4 and 50 h. The results demonstrate the synergistic effects of multi rare earth species for the improved CMAS resistance of RE-disilicates. Inert elements (Lu/Yb) benefit the maintaining of phase stability of the disilicate; and simulta-neously, active elements (Er/Tm) promote the precipitation of precipitated phase and reduce the corrosion ac-tivity by promptly change the composition of CMAS.
引用
收藏
页数:6
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