Microwave assisted solvent-free synthesis of dihydropyrimidinones by Biginelli reaction over Si-MCM-41 supported FeCl3 catalyst

被引：113
|
作者：
Choudhary, VR [1 ]
Tillu, VH [1 ]
Narkhede, VS [1 ]
Borate, HB [1 ]
Wakharkar, RD [1 ]
机构：
[1] Natl Chem Lab, Pune 411008, Maharashtra, India
来源：
CATALYSIS COMMUNICATIONS | 2003年 / 4卷 / 09期
关键词：
Biginelli reaction; synthesis of dihydropyrimidinones; FeCl3/Si-MCM-41;
D O I：
10.1016/S1566-7367(03)00111-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Among the Si-MCM-41 or montmorillonite K 10 clay supported ZnCl2, AlCl3, GaCl3, InCl3 and FeCl3 catalysts, FeCl3/Si-MCM-41 shows best performance for the microwave-assisted synthesis of dihydropyrimidinones by the Biginelli reaction involving multicomponent condensation of aromatic aldehyde, ethyl acetoacetate and urea in the absence of any solvent. It is a promising catalyst for the microwave-assisted reaction providing high product yield in a short period (3.0-5.0 min). (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：449 / 453
页数：5
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