Partial hydrogenation of 1,3-cyclooctadiene using dendrimer-encapsulated Pd-Rh bimetallic nanoparticles

被引：84
|
作者：
Chung, YM [1 ]
Rhee, HK [1 ]
机构：
[1] Seoul Natl Univ, Sch Chem Engn, Inst Chem Proc, Seoul 151742, South Korea
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2003年 / 206卷 / 1-2期
关键词：
dendrimer; nanoreactor; nanoparticle; bimetal; organic-inorganic composite; hydrogenation;
D O I：
10.1016/S1381-1169(03)00418-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This article reports the first effort for the preparation of Pd-Rh bimetallic nanoparticles in the presence of poly(amidoamine) dendrimers with surface hydroxyl groups (fourth generation, PAMAM-OH). The resulting dendrimer-encapsulated Pd-Rh bimetallic nanoparticles show a promising catalytic activity in partial hydrogenation of 1,3-cyclooctadiene. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：291 / 298
页数：8
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