Temperature dependent rate constants for O2(b) deactivation by O2(X)

被引：0
|
作者：
Tolstov, G. I. [1 ]
Zagidullin, M. V. [1 ,2 ]
Khvatov, N. A. [1 ,2 ]
Mebel, A. M. [1 ]
Mikheyev, P. A. [1 ,2 ]
Azyazov, V. N. [1 ,2 ]
机构：
[1] Samara Natl Res Univ, Samara 443086, Russia
[2] Lebedev Phys Inst, Samara 443011, Russia
来源：
2018 INTERNATIONAL CONFERENCE LASER OPTICS (ICLO 2018) | 2018年
关键词：
deactivation; singlet oxygen; collision; temperature dependence;
D O I：
暂无
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Rate constants for the deactivation of O-2(b) by collisions with O-2(X) have been determined in the temperature range from 297 to 800 K. O-2(h) was excited by pulses from a tunable dye laser, and the deactivation kinetics were followed by observing the temporal behavior of the b(1)Sigma(g) - X-3 Sigma(g) transition fluorescence. The deactivation rate constants for O-2 can be represented by the expression ko2=7.4x10(-17)xT(0.5)xexp(-1104.7 +/- 53.3/T).
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页码：85 / 85
页数：1
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