catena-Poly[[bis[2-(2-pyridyl)-1-H-imidazole-κ2N2,N3]cadmium]-μ-benzene-1,3-dicarboxylato-κ2O1:O3]

被引：1
|
作者：
Li, Chun-Jiang [1 ,2 ]
Lu, Jing-Mei [1 ]
Tu, Fan [1 ]
Chen, Jing-Ying [1 ]
Li, Yu-Jia [1 ]
机构：
[1] NE Normal Univ, Fac Life Sci, Changchun 130024, Peoples R China
[2] Jiamusi Univ, Sch Basic Med Sci, Jiamusi 154007, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
COORDINATION POLYMERS; PHOTOLUMINESCENCE; COMPLEXES; LIGANDS; SERIES;
D O I：
10.1107/S1600536811001243
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title coordinaltion polymer, [Cd(C8H4O4)(C8H7N3)(2)](n), the Cd-II atom, lying on a twofold rotation axis, is six-coordinated by two carboxylate O atoms from two benzene-1,3-dicarboxylate (m-BDC) ligands and four N atoms from two chelating 2-(2-pyridyl)imidazole molecules, forming a slightly distorted octahedral geometry. The m-BDC ligand is located over a twofold rotation axis. The Cd-II atoms are bridged by the m-BDC ligands, leading to a wave-shaped chain structure along [010]. N-H center dot center dot center dot O hydrogen bonds connect the chains.
引用
收藏
页码：M269 / U1787
页数：11
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