First example of a hydrogen-bonded three-dimensional Pillared structure involving an organotin motif:: Synthesis and X-ray crystal structures of {[nBu2Sn(H2O)3(L)Sn(H2O)3nBu2]2+[L]2-}•2MeOH•2H2O and {[Ph3Sn(L)Sn(H2O)Ph3]n}•THF (L=1,5-naphthalenedisulfonate)

被引：0
|
作者：
Chandrasekhar, V [1 ]
Boomishankar, R
Steiner, A
Bickley, JF
机构：
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] Univ Liverpool, Liverpool L69 7ZD, Merseyside, England
来源：
ORGANOMETALLICS | 2003年 / 22卷 / 17期
关键词：
D O I：
10.1021/om030423k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of a disulfonic acid with (Bu3SnOSnnBu3)-Bu-n generates the Sn-alkyl-cleaved dicationic species {[(Bu2Sn)-Bu-n(H2O)(3)(L)Sn(H2O)(3)Bu-n(2)](2+)[L](2-)}.2MeOH.2H(2)O (4; L = 1,5-naphthalenedisulfonate, 1,5-C10H6-(SO3)(2)). The corresponding reaction with Ph-3-SnOSnPh3 leads to the unusual zigzag polymer {[Ph-3-Sn(L)Sn(H2O)Ph-3](n)}.THF (5), which contains an Sn-O motif in the backbone as well as a pendant group.
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页码：3342 / 3344
页数：3
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