Oxygen-atom transfer photochemistry of a molecular copper bromate complex

被引：4

作者：

Van Trieste, Gerard P. ^{[1
]}

Reibenspies, Joseph H. ^{[1
]}

Chen, Yu-Sheng ^{[2
]}

Sengupta, Debabrata ^{[1
]}

Thompson, Richard R. ^{[1
]}

Powers, David C. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Univ Chicago, ChemMatCARS, Argonne, IL 60439 USA

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 90期

关键词：

D O I：

10.1039/d2cc04403j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis and oxygen-atom transfer (OAT) photochemistry of [Cu(tpa)BrO3]ClO4. In situ spectroscopy and in crystallo experiments indicate OAT proceeds from a Cu-O fragment generated by sequential Cu-O bond cleavage and OAT from BrOx to [Cu(tpa)](+). These results highlight synthetic opportunities in M-O photochemistry and demonstrate the utility of in crystallo experiments to evaluating photochemical reaction mechanisms.

引用

页码：12608 / 12611

页数：4

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