Surface nucleation-induced fluoropolymer Janus nanoparticles via emulsifier-free batch-seeded emulsion polymerization

被引：41

作者：

Pan, Mingwang ^{[1
]}

Yang, Lianyun ^{[2
]}

Guan, Bing ^{[2
]}

Lu, Maosheng ^{[2
]}

Zhong, Ganji ^{[3
]}

Zhu, Lei ^{[2
]}

机构：

[1] Hebei Univ Technol, Inst Polymer Sci & Engn, Tianjin 300130, Peoples R China

[2] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA

[3] Sichuan Univ, Coll Polymer Sci & Engn, Chengdu 610065, Peoples R China

来源：

SOFT MATTER | 2011年 / 7卷 / 23期

关键词：

NONSPHERICAL COLLOIDAL PARTICLES; ANISOTROPIC PARTICLES; INTERFACIAL PHENOMENA; LATEX-PARTICLES; MORPHOLOGY; MICROPARTICLES; NETWORKS;

D O I：

10.1039/c1sm06498c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nonspherical poly(vinylidene fluoride)/polystyrene (PVDF/PS) composite latex particles were prepared via a facile emulsifier-free batch-seeded emulsion polymerization. It was found that the styrene (St)/PVDF feed ratio was a determining factor for the formation of well-defined Janus particles. Transmission electron microscopy study revealed that the immiscibility between PVDF and St-swollen PS (PS/St) was the driving force for the dewetting and nucleation of PS/St bulges on the PVDF particle surface. When the St/PVDF feed ratio was high, easy fusion of multiple PS/St bulges into one single bulge on the PVDF particle resulted in well-defined PVDF/PS Janus particles. When the St/PVDF feed ratio was low, it was difficult for multiple bulges to fuse together to form PVDF/PS Janus particles.

引用

页码：11187 / 11193

页数：7

共 50 条

[1] Synthesis of polytetrafluoroethylene/polyacrylate core-shell nanoparticles via emulsifier-free seeded emulsion polymerization
Xuejun Cui
Shuangling Zhong
Jia Xu
Hongyan Wang
Colloid and Polymer Science, 2007, 285 : 935 - 940
[2] Conducting polyaniline nanoparticles encapsulated with polyacrylate via emulsifier-free seeded emulsion polymerization and their electroactive films
Chen, Fei
Liu, Peng
CHEMICAL ENGINEERING JOURNAL, 2011, 168 (02) : 964 - 971
[3] Synthesis of polytetrafluoroethylene/polyacrylate core-shell nanoparticles via emulsifier-free seeded emulsion polymerization
Cui, Xuejun
Zhong, Shuangling
Xu, Jia
Wang, Hongyan
COLLOID AND POLYMER SCIENCE, 2007, 285 (08) : 935 - 940
[4] Synthesis of polystyrene-silica nanoparticles via RAFT emulsifier-free emulsion polymerization
Tumnantong, Dusadee
Rempel, Garry L.
Prasassarakich, Pattarapan
EUROPEAN POLYMER JOURNAL, 2016, 80 : 145 - 157
[5] PARTICLE NUCLEATION IN EMULSION POLYMERIZATION .2. NUCLEATION IN EMULSIFIER-FREE SYSTEMS INVESTIGATED BY SEED POLYMERIZATION
HANSEN, FK
UGELSTAD, J
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1979, 17 (10) : 3033 - 3045
[6] Effects of surface charge density on emulsion kinetics and secondary particle formation in emulsifier-free seeded emulsion polymerization of methyl methacrylate
I. -W. Cheong
J. -H. Kim
Colloid and Polymer Science, 1997, 275 : 736 - 743
[7] Effects of surface charge density on emulsion kinetics and secondary particle formation in emulsifier-free seeded emulsion polymerization of methyl methacrylate
Cheong, IW
Kim, JH
COLLOID AND POLYMER SCIENCE, 1997, 275 (08) : 736 - 743
[8] Synthesis and surface characterization of an amphiphilic fluorinated copolymer via emulsifier-free emulsion polymerization of RAFT
Xu, Shouping
Liu, Weiqu
JOURNAL OF FLUORINE CHEMISTRY, 2008, 129 (02) : 125 - 130
[9] Emulsifier-free emulsion polymerization of methyl methacrylate containing hydrophilic magnetite nanoparticles
Seda Beyaz
Taner Tanrisever
Hakan Kockar
Macromolecular Research, 2010, 18 : 1154 - 1159
[10] Emulsifier-Free Emulsion Polymerization of Methyl Methacrylate Containing Hydrophilic Magnetite Nanoparticles
Beyaz, Seda
Tanrisever, Taner
Kockar, Hakan
MACROMOLECULAR RESEARCH, 2010, 18 (12) : 1154 - 1159

← 1 2 3 4 5 →