Macrodistribution of anodic dissolution rate at a rotating disk electrode with partially insulated surface

被引:0
|
作者
Dikusar, AI
Redkozubova, OO
Yushchenko, SP
Kriksunov, LB
Harris, D
机构
[1] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
[2] Buckbee Mears Cortland, Cortland, NY 13045 USA
关键词
electrochemical micromachining; anodic dissolution; current distribution; etching in the presence of masks; rotating disk electrode;
D O I
10.1023/A:1026139907837
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Macrodistribution of etching rates of a macroscopically nonuniform, partially "dipped," rotating disk electrode of low-carbon steel in 1 M NaCl at pH 1 with photoresist insulation and the density of active rectangular holes being similar to1.6 holes/mm(2) is studied at dimensionless etching rates i(avg)(0)/i(l) = 0.2-1.1, where i(avg)(0) is the average current density per active surface and i(l) the limiting anodic current density determined by the ionic transport rate. The distribution of the average etching rates in the normal direction is determined by the primary current distribution and is insensitive towards the type of the dissolution rate distribution in a cavity.
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页码:1134 / 1136
页数:3
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