1,4-Naphthalenedicarboxylic acid functionalized phosphomolybdate: Synthesis, crystal structure and optical properties

被引：9
|
作者：
Huang-Fu, You-Jing [1 ]
Chen, Xue-Yan [1 ]
Yang, Wei [1 ]
Bai, Yan [1 ,2 ]
Dang, Dong-Bin [1 ]
机构：
[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Key Lab Polyoxometalate Chem Henan Prov, Kaifeng 475004, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
MATERIALS LETTERS | 2015年 / 155卷
关键词：
Polyoxometalate; Carboxylic acid; Crystal structure; Luminescence; LUMINESCENT PROPERTIES; POLYOXOMETALATE; LIGAND; CLUSTER; CONSTRUCTION; POLYMERS;
D O I：
10.1016/j.matlet.2015.04.102
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
One inorganic-organic hybrid phosphomolybdate H-12[(PMo6O21)(2)(1,4-NDC)(3)]center dot 37.5H(2)O (1) (1,4H(2)NDC=1,4-naphthalenedicarboxylic acid) has been synthesized and well-characterized. Compound 1 exhibits a lantern-type dimer constructed by Mo-O-C bonds between a couple of [PM06021](3-) polyoxoanions and three 1,4-NDC2- ligands, and displays obvious fluorescent emission at room temperature as a result of the use of functional organic component. The spectroscopic experiments show that compound 1 displays a sensitive and reversible fluorescence response to the pH values in the aqueous solution. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：48 / 50
页数：3
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