Facile synthesis of magnetic homochiral metal-organic frameworks for "enantioselective fishing''

被引：57
|
作者：
Chang, Cui-Lan [1 ]
Qi, Xiao-Yue [1 ]
Zhang, Jiang-Wei [2 ]
Qiu, Ya-Ming [3 ]
Li, Xian-Jiang [1 ]
Wang, Xin [1 ]
Bai, Yu [1 ]
Sun, Jun-Liang [3 ]
Liu, Hu-Wei [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Inst Analyt Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 17期
基金：
中国国家自然科学基金;
关键词：
CHROMATOGRAPHIC RESOLUTION; ASYMMETRIC CATALYSIS; HYDROGEN STORAGE; SEPARATION; ADSORPTION; SULFOXIDES; ENANTIOSEPARATION; RECOGNITION; CHEMISTRY; CHIRALITY;
D O I：
10.1039/c4cc09988e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Magnetic functionalized homochiral metal-organic frameworks (MOFs) were prepared and applied to efficient enantioselective fishing of chiral drug intermediates. Under optimized conditions, the enantiomeric excess (ee) value as high as 85.2% was achieved for methyl phenyl sulfoxide (MPS) within 3 min.
引用
收藏
页码：3566 / 3569
页数：4
相关论文
共 50 条
  • [1] Enantioselective catalysis with homochiral metal-organic frameworks
    Ma, Liqing
    Abney, Carter
    Lin, Wenbin
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) : 1248 - 1256
  • [2] Computational screening of homochiral metal-organic frameworks for enantioselective adsorption
    Bao, Xiaoying
    Broadbelt, Linda J.
    Snurr, Randall Q.
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 157 : 118 - 123
  • [3] Homochiral Metal-Organic Frameworks for Enantioselective Separations in Liquid Chromatography
    Corella-Ochoa, Nieves
    Tapia, Jesus B.
    Rubin, Heather N.
    Lillo, Vanesa
    Gonzalez-Cobos, Jesus
    Luis Nunez-Rico, Jose
    Balestra, Salvador R. G.
    Almora-Barrios, Neyvis
    Lledos, Marina
    Guell-Bara, Arnau
    Cabezas-Gimenez, Juanjo
    Escudero-Adan, Eduardo C.
    Vidal-Ferran, Anton
    Calero, Sofia
    Reynolds, Melissa
    Marti-Gastaldo, Carlos
    Ramon Galan-Mascaros, Jose
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (36) : 14306 - 14316
  • [4] Molecular modeling of enantioselective adsorption in homochiral metal-organic frameworks
    Bao, Xiaoying
    Broadbelt, Linda J.
    Snurr, Randall Q.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [5] Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation
    Li, Xianjiang
    Chang, Cuilan
    Wang, Xin
    Bai, Yu
    Liu, Huwei
    [J]. ELECTROPHORESIS, 2014, 35 (19) : 2733 - 2743
  • [6] Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties
    Centrone, Andrea
    Harada, Takuya
    Speakman, Scott
    Hatton, T. Alan
    [J]. SMALL, 2010, 6 (15) : 1598 - 1602
  • [7] Chiral templated synthesis of homochiral metal-organic frameworks
    Berijani, Kayhaneh
    Chang, Li-Mei
    Gu, Zhi-Gang
    [J]. COORDINATION CHEMISTRY REVIEWS, 2023, 474
  • [8] Enantioselective adsorption in homochiral metal-organic frameworks: the pore size influence
    Gu, Zhi-Gang
    Grosjean, Sylvain
    Braese, Stefan
    Woell, Christof
    Heinke, Lars
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (43) : 8998 - 9001
  • [9] Homochiral metal-organic frameworks for enantioseparation
    Liu, Juan
    Mukherjee, Soumya
    Wang, Fei
    Fischer, Roland A.
    Zhang, Jian
    [J]. CHEMICAL SOCIETY REVIEWS, 2021, 50 (09) : 5706 - 5745
  • [10] Synthesis of a Homochiral Metal-Organic Zeolite for Enantioselective Sensing and Separation
    Li, Min-Yu
    Wang, Fei
    Zhang, Jian
    [J]. CRYSTAL GROWTH & DESIGN, 2020, 20 (09) : 5644 - 5647
12345