Synthesis of ultrahigh molar mass, structural defects free poly(vinyl chloride) with high syndiotacticity and glass transition temperature by single electron transfer-degenerative chain transfer living radical polymerization (SET-DTLRP)

被引：35

作者：

Percec, V ^{[1
]}

Ramirez-Castillo, E ^{[1
]}

Hinojosa-Falcon, LA ^{[1
]}

Popov, AV ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2005年 / 43卷 / 10期

关键词：

iodoform; kinetics (polym.); living polymerization; poly(vinyl chloride); radical polymerization; sodium dithionite; vinyl chloride;

D O I：

10.1002/pola.20650

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Synthesis of Ultrahigh Molar Mass, Structural Defects Free Poly(Vinyl Chloride) with High Syndiotacticity and Glass Transition Temperature by Single Electron Transfer-Degenerative Chain Transfer Living Radical Polymerization (SET-DTLRP) .

引用

页码：2185 / +

页数：4

共 20 条

[1] Synthesis of High Glass Transition Temperature Copolymers Based on Poly(vinyl chloride) via Single Electron Transfer-Degenerative Chain Transfer Mediated Living Radical Polymerization (SET-DTLRP) of Vinyl Chloride in Water
Coelho, Jorge F. J.
Mendonca, Patricia V.
Popov, Anatoliy V.
Percec, Virgil
Goncalves, Pedro M. O. F.
Gil, Maria Helena
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (24) : 7021 - 7031
[2] Acceleration of the single electron transfer-degenerative chain transfer mediated living radical polymerization (SET-DTLRP) of vinyl chloride in water at 25°C
Percec, V
Popov, AV
Ramirez-Castillo, E
Weichold, O
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (24) : 6364 - 6374
[3] Single electron transfer-degenerative chain transfer mediated living radical polymerization (SET-DTLRP) of vinyl chloride initiated with methylene iodide and catalyzed by sodium dithionite
Percec, V
Popov, AV
Ramirez-Castillo, E
Coelho, JFJ
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (04) : 773 - 778
[4] Tuning the viscoelastic features required for 3D printing of PVC-acrylate copolymers obtained by single electron transfer-degenerative chain transfer living radical polymerization (SET-DTLRP)
Calafel, M. I.
Aguirresarobe, R. H.
Sadaba, N.
Boix, M.
Conde, J. I.
Pascual, B.
Santamaria, A.
EXPRESS POLYMER LETTERS, 2018, 12 (09): : 824 - 835
[5] Phase transfer catalyzed single electron transfer-degenerative chain transfer mediated living radical polymerization (PTC-SET-DTLRP) of vinyl chloride catalyzed by sodium dithionite and initiated with iodoform in water at 43 °C
Percec, V
Popov, AV
Ramirez-Castillo, E
Coelho, JFJ
Hinojosa-Falcon, LA
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (04) : 779 - 788
[6] Functionalization of the active chain ends of poly(vinyl chloride) obtained by single-electron-transfer degenerative-chain-transfer mediated living radical polymerization:: Synthesis of telechelic α,ω-di(hydroxy)poly(vinyl chloride)
Percec, V
Popov, AV
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (06) : 1255 - 1260
[7] Synthesis of ultrahigh molar mass poly(2-hydroxyethyl methacrylate) by single-electron transfer living radical polymerization
Nguyen, Nga H.
Leng, Xuefei
Percec, Virgil
POLYMER CHEMISTRY, 2013, 4 (09) : 2760 - 2766
[8] Scaling-up of poly(vinyl chloride) prepared by single electron transfer-degenerative chain transfer mediated living radical polymerization in water media-II: High molecular weight-ultra stable PVC
Coelho, Jorge F. J.
Fonseca, A. C.
Goncalves, Pedro M. O. F.
Popov, Anatoliy V.
Gil, M. H.
CHEMICAL ENGINEERING SCIENCE, 2012, 69 (01) : 122 - 128
[9] Thermal and mechanical characterization of poly(vinyl chloride)-b-poly(butyl acrylate)-b-poly(vinyl chloride) obtained by single electron transfer -: degenerative chain transfer living radical polymerization in water
Coelho, Jorge F. J.
Carreira, Mafalda
Popov, Anatoliy V.
Goncalves, Pedro M. O. F.
Gil, M. H.
EUROPEAN POLYMER JOURNAL, 2006, 42 (10) : 2313 - 2319
[10] Thermal and mechanical characterization of poly(vinyl chloride)-b-poly(butyl acrylate)-b-poly(vinyl chloride) obtained by single electron transfer - degenerative chain transfer living radical polymerization in water
Coelho, Jorge F.J.
Carreira, Mafalda
Popov, Anatoliy V.
Gonçalves, Pedro M.O.F.
Gil, M.H.
European Polymer Journal, 2006, 42 (10): : 2313 - 2319

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