Hydrothermal synthesis of Pt-Ru/MWCNTs and its electrocatalytic properties for oxidation of methanol

被引:0
|
作者
Sun Jingyu [1 ]
Huang Jianshu [1 ]
Cao Yanxia [3 ]
Zhang Xiaogang [1 ,2 ]
机构
[1] Xinjiang Univ, Inst Appl Chem, Urumqi 830046, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R China
[3] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou, Peoples R China
来源
关键词
Pt-Ru/MWCNTs electrocatalyst; methanol electro-oxidation; hydrothermal method;
D O I
暂无
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Pt-Ru nanoparticles supported on multiwalled carbon nanotube (MWCNTs) were synthesized by hydrothermal method. The catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS). Pt-Ru nanoparticles uniformly dispersed on MWCNTs with the mean diameter of about 3.5 nm. The electro-catalytic oxidation of methanol was studied by cyclic voltammetry, chronoamperometry and impedance spectroscopy in 0.5 M H2SO4 solution containing 1.0 M CH3OH. The results showed that the Pt-Ru/MWCNTs catalysts as prepared had higher electrocatalytic activities for methanol oxidation than that of Pt-Ru/MWCNTs synthesized by microwave heating method.
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页码:64 / 71
页数:8
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