Synthesis of the Hydroxide Cluster [Al13(μ3-OH)6(μ-OH)18(H2O)24]15+ from an Aqueous Solution

被引：60

作者：

Wang, Wei ^{[1
]}

Wentz, Katherine M. ^{[2
]}

Hayes, Sophia E. ^{[2
]}

Johnson, Darren W. ^{[3
]}

Keszler, Douglas A. ^{[1
]}

机构：

[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA

[2] Washington Univ, Dept Chem, St Louis, MO 63130 USA

[3] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 11期

基金：

美国国家科学基金会;

关键词：

CRYSTAL STRUCTURES; ALUMINUM; NMR;

D O I：

10.1021/ic200483q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A scalable synthesis of the "flat" tridecameric inorganic cluster [Al-13(mu(3)-OH)(6)(mu-OH)(18)(H2O)(24)](15+) has been realized by treating an aqueous aluminum nitrate solution with a zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO3)(3). Products have been characterized by X-ray diffraction and solid-state Al-27 MAS and MQMAS NMR.

引用

页码：4683 / 4685

页数：3

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