Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases

被引：51
|
作者：
Beyler, Maryline [1 ]
Ezzaher, Salah [1 ]
Karnahl, Michael [1 ]
Santoni, Marie-Pierre [1 ]
Lomoth, Reiner [1 ]
Ott, Sascha [1 ]
机构：
[1] Uppsala Univ, Dept Photochem & Mol Sci, Angstrom Labs, S-75120 Uppsala, Sweden
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 42期
基金：
瑞典研究理事会;
关键词：
ACTIVE-SITE; CRYSTAL-STRUCTURE; COORDINATION; CHALLENGES; REDUCTION; CARBONYL;
D O I：
10.1039/c1cc14449a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mononuclear pentacoordinate iron complexes with a free coordination site were prepared as mimics of the distal Fe (Fe(d)) in the active site of [FeFe] hydrogenases. The complexes catalyze the electrochemical reduction of protons at mild overpotential.
引用
收藏
页码：11662 / 11664
页数：3
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