Synthesis, Structure and Optical Properties of a D-π-A Type 2,2′:6′,2"-Terpyridine Derivative

被引：0
|
作者：
Gao Yuan-Hao [1 ]
Tian Yu-Peng [2 ]
Yang Jia-Xiang [2 ]
Yang Feng-Ling [1 ]
Li Jing [1 ]
Zheng Zhi [1 ]
机构：
[1] Xuchang Univ, Inst Surface Micro & Nano Mat, Xuchang 461000, Peoples R China
[2] Anhui Univ, Dept Chem, Hefei 230039, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2011年 / 32卷 / 08期
关键词：
Terpyridine derivative; Single crystal structure; Single-photon property; Two-photon property; SERUM IRON; COMPLEXES; TERPYRIDINES; POLYMERS; LIGANDS; REAGENT; ZN(II);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A D-pi-A type 2,2': 6',2 ''-terpyridine derivative was synthesized by Wittig reaction using 2,2': 6',2 ''-terpyridine as an acceptor (A) and 3-formyl-N-hexylcarbazole as a donor (D), its structure was characterized by means of MS, FTIR, (1)H NMR, (13)C NMR and single crystal X-ray diffraction. For the D-pi-A type terpyridine derivative, its linear absorption, single- and two-photon properties were measured and the results showed that the target compound has good fluorescence with the fluorescence quantum yield (Phi) up to 0.46 and the maximal two-photon absorption cross section (delta) up to 120 GM.
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页码：1755 / 1760
页数：6
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