Photocatalytic behaviour of zinc tetraamino phthalocyanine-silver nanoparticles immobilized on chitosan beads

Photocatalytic degradation of Rhodamine 6G using unconjugated zinc tetraamino phthalocyanine (ZnTAPc) or when conjugated to Ag nanoparticles (ZnTAPc-AgNPs) is reported. Upon conjugating ZnTAPc to silver nanoparticles, the singlet oxygen production of the phthalocyanine was slightly increased. ZnTAPc and ZnTAPc-AgNPs were immobilized onto chitosan beads for ease of recovery after photocatalysis. Chitosan beads were characterized by FTIR, XRD and TGA. The photodegradation of Rhodamine 6G was used to evaluate the efficiency of the immobilized photocatalysts. In the presence of AgNPs, the photodegradation of Rhodamine 6G was enhanced. The apparent rates (k) were found to be 8.51 x 10(-8) and 1.61 x 10(-7) mol L-1 min(-1) for chitosan supported ZnTAPc or ZnTAPc-AgNPs, respectively. The observation of good photocatalytic activity of the ZnTAPc when immobilized on chitosan proves the uncompromised efficiency of the photocatalysts even when confined in beads, showing great potential for the functionalized beads as heterogeneous catalysts. (c) 2015 Elsevier B.V. All rights reserved.