Synthesis of a new cubic phase in the B-C-N system

被引：13
|
作者：
Filonenko, V. P. [1 ]
Khabashesku, V. N. [2 ,3 ]
Davydov, V. A. [1 ]
Zibrov, I. P. [4 ]
Agafonov, V. N. [5 ]
机构：
[1] Russian Acad Sci, Vereshchagin Inst High Pressure Phys, Troitsk 142190, Moscow Oblast, Russia
[2] Rice Univ, Dept Chem, Rice Quantum Inst, Houston, TX 77005 USA
[3] Rice Univ, Ctr Nanoscales Sci & Technol, Houston, TX 77005 USA
[4] Russian Acad Sci, AV Shubnikov Crystallog Inst, Moscow 119333, Russia
[5] Univ Tours, F-37041 Tours 01, France
来源：
INORGANIC MATERIALS | 2008年 / 44卷 / 04期
关键词：
D O I：
10.1134/S0020168508040122
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Phase formation in the B - C - N system has been studied at pressures from 6 to 15 GPa and temperatures from 1000 to 1600 degrees C using mixtures of carbon nitride ( C-3 N-4) nanospheres and boron. A new ternary phase with the structure of cubic boron nitride in which some of the nitrogen and boron atoms are replaced by carbon has been obtained at p similar or equal to 8 GPa and t similar or equal to 1500 degrees C. According to the Rietveld refinement results, its composition is BC0.47N0.85.
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收藏
页码：395 / 400
页数：6
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